An-Najah National University

Hikmat S. Hilal\\\'s Blog

1) Advanced Materials & Nanotech 2) Homogeneous and heterogeneous catalysis 3) Water purification 4) Renewable Energies 5) Semiconductor Surface Modification 6) Thin Film preparation and Characterization

 
  • Bookmark and Share Email
     
  • Wednesday, January 1, 1986
  • Homogeneous catalysis of the reaction of silanes with alcohols using Mn2(CO)10
  • Published at:Not Found
  • H. S. Hilal*, S. Khalaf, M. Al-Nouri, and Maha Karmi, J. Mol. Catal., 35(1986)137-142.

     

    Abstract

    Dimanganese decacarbonyl catalyst has been evaluated in the reactions of HSiR3 (R = Et, OEt) with R'OH (R' = Me, Et, i-Pr, t-Bu and benzyl), under various conditions. The order of reactivity of the alcohols decreases when more bulky alkyl groups are used, and that of the silanes increases if a more electron-withdrawing group (OEt) is used. Kinetic analysis indicates that the reaction is first order with respect to the silane, to the alcohol and to the catalyst. The effects of varying the solvent and adding a phosphine ligand have also been investigated.

     

     

     

     
  • Bookmark and Share Email
     
Leave a Comment

Attachments

  • No Attachments Found for this Article

PROFILE

Hikmat S. Hilal
Organometallics (organic and inorganic), Materials, Catalysis, Semiconductors, Photoelectro-chemistry
 
Show Full ProfileEnglish CV Arabic CV
 
 

PUBLISHED ARTICLES

GENERAL POSTS

 
Please do not email me if you do not know me
Please do not e-mail me if you do not know me